The synthesis and optical activity of novel chiral dendrimers with axial chirality are reported. The dendrimers were constructed by coupling of the polyether dendritic bromides with (R)-(+)-1,1ะ-bi-2-naphthol (1). The uniform (2, 3, 4) and nonuniform double-O-alkylated (8, 9, 10) as well as mono-O-a
โฆ LIBER โฆ
Dendrimers and chirality
โ Scribed by Chris W. Thomas; Yitzhak Tor
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 405 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0899-0042
- DOI
- 10.1002/chir.10
No coin nor oath required. For personal study only.
โฆ Synopsis
The preparation, chiroptical properties and potential application of chiral dendritic polymers are reviewed. Mislow's analysis of the manifestation of chirality, cryptochirality and fuzzy chirality is useful in studying these unique chiral macromolecules.
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## FIGURE 1 Four structural components of dendrimers.