Versatile Conversion of N-Heterocyclic S
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Dr. Yun Xiong; Dr. Shenglai Yao; Prof. Dr. Matthias Driess
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Article
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2012
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John Wiley and Sons
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English
⚖ 270 KB
The facile one-pot reaction of the stable N-heterocyclic silylene LSi: 1 (L=(ArN)C(=CH(2))CH=C(Me)(NAr), Ar=2,6-iPr(2)C(6)H(3)) with Me(2)Zn, Me(3)Al, H(3)Al-NMe(3), and MeLi has been investigated. The silicon(II) atom in 1 is capable of insertion into the corresponding M-C and Al-H bonds under very