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Demonstration of “Sulfene” Insertion into the Metal-Hydrogen Bond

✍ Scribed by Dr. Ingo-Peter Lorenz


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
223 KB
Volume
17
Category
Article
ISSN
0044-8249

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Versatile Conversion of N-Heterocyclic S
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The facile one-pot reaction of the stable N-heterocyclic silylene LSi: 1 (L=(ArN)C(=CH(2))CH=C(Me)(NAr), Ar=2,6-iPr(2)C(6)H(3)) with Me(2)Zn, Me(3)Al, H(3)Al-NMe(3), and MeLi has been investigated. The silicon(II) atom in 1 is capable of insertion into the corresponding M-C and Al-H bonds under very