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Demasking of cyanide complexes. Application to reactions with dimethylglyoxime

✍ Scribed by F. Burriel-Marti; F. Pino-Perez


Book ID
102982363
Publisher
Elsevier Science
Year
1950
Tongue
English
Weight
565 KB
Volume
4
Category
Article
ISSN
0003-2670

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Reaction of cyanide with hydroxamic acid
✍ Thomas Emery πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 364 KB

At high pH primary hydroxamic acid-iron complexes react rapidly with potassium cyanide to yield a deep blue iron complex. Secondary, or N-substituted, monohydroxamic acid-iron complexes also react with loss of the red color typical of these complexes but with no formation of the blue product. Under