Delocalized carbanions: synthesis and polymerization of 2,3-disubstituted-1,3-butadienes
โ Scribed by Bernard Gordon; Mitchell Blumenthal
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 217 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0170-0839
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The reactions of aluminum hydride Morgantown, West Virginia 26506 trimethylsilyl-substitutedu-allenic alcohols with lithium afforded 2-(trimethylsilyl)-1,3\_butadienes. Diels-Alder reactions of 2-(trialkylsilyl)-1,3-butadienes are receiving increasing attention.
2,3-Bis(braruxnethyl)-1,3-butadiene (A) has been obtained before by thermal deccmposition of its sulfone and was described as a light-senstivie solid, which polymerized readily in most solvents. 1 We have now prepared 1 by a different procedure and found that although it polymerized quite rapidly i