Dehydrotropylium–Co2(CO)6 Ion: Generation, Reactivity and Evaluation of Cation Stability
✍ Scribed by Sheida Amiralaei; Prof. James Gauld; Prof. James R. Green
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 410 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Two stereoisomers of [Ru(terpy)(bpyO)(CO)](PF~6~) ([1]^+^ and [2]^+^; terpy = 2,2′:6′,2′′‐terpyridine, bpyO = 2,2′‐bipyridin‐6‐onato) were prepared. The pyridonato moiety in the bpyO ligand of [1]^+^ and [2]^+^ is located __trans__ and __cis__, respectively, to CO. Treatment of [1]^+^ a
H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety