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Dehydrohalogenation and cleavage reactions in silicon-nitrogen-boron systems. Reactions of bis(trimethylsilyl)aminotrimethylsilylaminochloroborane

✍ Scribed by Wells, Richard L.; Collins, Alva Leroy


Book ID
118059371
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
510 KB
Volume
7
Category
Article
ISSN
0020-1669

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Lithium reduction of (Z)-l,2-bis(trimethylsilyl)-l-phenylethene (l) yields the dianion of the (E)-isomer (3) and via Schlenk dimerization dilithium 1.4-diyl-l,4-diphenyl-l,2,3,4-tetrakis(trimethylsilyl)butane (4). The NMR parameters for both systems are reported and their solution structures are dis