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Dehydrogenative Coupling Reactions between a Monosubstituted Alkyne and Monosilane in the Presence of Lithium Aluminum Hydride

✍ Scribed by Itoh, Masayoshi; Kobayashi, Mineo; Ishikawa, Junichi


Book ID
127030679
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
89 KB
Volume
16
Category
Article
ISSN
0276-7333

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Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T