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Dehydrogenation of 1,3-butanediol over Cu-based catalyst

โœ Scribed by Satoshi Sato; Ryoji Takahashi; Hiromitsu Fukuda; Kanichiro Inui

Book ID
108212905
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
340 KB
Volume
272
Category
Article
ISSN
1381-1169

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Dehydration of 1,4-butanediol was investigated over ZrO 2 at temperatures of 325-375 โ€ข C. Modification of ZrO 2 with a small amount of sodium hydroxide greatly enhanced the selectivity to 3-buten-1-ol. Temperature-programmed desorption of adsorbed NH 3 and CO 2 elucidated acidity and basicity of the