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Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

✍ Scribed by Dobereiner, Graham E.; Crabtree, Robert H.

Book ID
118168182
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
694 KB
Volume
110
Category
Article
ISSN
0009-2665

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## Abstract Among a large variety of fine‐tuning parameters for homogeneous catalysts the net charge of transition‐metal complexes appear to be an interesting factor that considerably affects activation of substrates and catalytic activity in general. The electrophilicity of coordinated alkenes in