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Dehydrocoupling of Silanes Catalyzed by Zirconocene- and Titanocene Alkyne Complexes

โœ Scribed by Normen Peulecke; Dominique Thomas; Wolfgang Baumann; Christine Fischer; Uwe Rosenthal

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
233 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Thezirconocene-and titanocene alkyne complexes 1-10 were tested to be effective catalysts in the dehydrocoupling of hydrosilanes like PhMeSiHz and PhJ3iHz to give oligomers and of other examples, e.g., PhSiHs polymers with cyclic oligosikmesas byproducts. @ 1997 Elsevier Science Ltd.

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