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Dehydrochlorination--decarbonylation of 2-chloro-1,3-dicarbonyl compounds, a method for ring contraction

โœ Scribed by Buechi, George; Hochstrasser, Ulrich; Pawlak, Waltraud

Book ID
126023227
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
406 KB
Volume
38
Category
Article
ISSN
0022-3263

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1-Amino-2-chloromethylene-2,3-dihydropyr
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โœ Orazio A Attanasi; Paolino Filippone; Chiara Fiorucci; Fabio Mantellini ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 144 KB

Ncsv l-amin~2-chlommethylene-2,3-dih~dropyrrolcs, predominantly as E isomers, have been obtained in go~ yields and under mild conditions by the sodium hydride catalyzed reaction of ~me conjugated azt~kenes with 2-chloro-1,3-dicarbonyl c~mapounds.