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Dehydrobromination of secondary and tertiary alkyl and cycloalkyl bromides with 1,8-diazabicyclo[5.4.0]undec-7-ene. Synthetic applications

✍ Scribed by Wolkoff, Peder


Book ID
120836025
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
685 KB
Volume
47
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Reactions of 1,3-Di
✍ S. ELSHEIMER; C. J. FOTI; M. D. BARTBERGER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

Diazabicyclo( 5.4 .0)undec-7-ene. -Treatment of halogen compounds (I) with DBU is investigated in order to obtain fluorinated dienes for cycloaddition reactions. However, the expected products (cf. (II)) are only obtained in the case of aryl substituents. Alkyl, cycloalkyl and alkoxy substituents