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Dehydrative Fragmentation of 5-Hydroxyalkyl-1 H -tetrazoles: A Mild Route to Alkylidenecarbenes

✍ Scribed by Wardrop, Duncan J.; Komenda, John P.


Book ID
118208896
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
328 KB
Volume
14
Category
Article
ISSN
1523-7060

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This work describes the first and unprecedented examples of inverse electron demand Diels-Alder reactions of 5-(1-nitrosovinyl)-1-phenyl-1H-tetrazole, generated in situ from the corresponding bromooxime, with electron rich alkenes and heterocycles, providing in good overall yields tetrazolyl-1,2-oxa