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Dehydration reactions in the mass spectra of 13-podocarpen-12-ols and 12-podocarpen-14-ols

✍ Scribed by Inger Wahlberg; Curt R. Enzell


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
430 KB
Volume
12
Category
Article
ISSN
1076-5174

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Stereospecific 1,3 and 1,4 dehydration r
✍ Inger Wahlberg; Kerstin Karlsson; Curt R. Enzell πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 890 KB

## Abstract Specific deuterium labelling revealed that podocarpan‐12α‐ and ‐14α‐01, representing conformationally well defined cyclohexanols, eliminate water mainly by stereospecific 1,3 reactions involving __cis__ tertiary hydrogens on electron‐impact. Dehydration of podocarpan‐12ΓŸβ€0l, which also