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Dehalogenation of α -haloketones and vic-dibromides with nickel boride

✍ Scribed by JC Sarma; M Borbaruah; R.P. Sharma

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
218 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

I @-Haloketones and vie-dibromides are converted to the corresponding ketones and alkenes respectively with nickel boride generated in situ from sodium borohydride and nickel chloride. During the course of our studies on in situ generated nickel boridel, it was observed that a carbonyl group remains unaftected under appropriate reaction conditions. 2 It was therefore argued that since reductive removal or a halogen in d.-haloketones can sometimes be achieved through hyorogenation3, nickel boride whose generation from sodium borohydride and nickel chloride is accompanied by a sufticient amount of hydrogen evolution 4 ,

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