DEHALOGENATION OF 7,7-BIS(BROMOMETHYL) BICYCLO[4.1.0]HEPT-3-ENE
β Scribed by Craig, Mary D.; Mazzocchi, Paul H.
- Book ID
- 120331769
- Publisher
- Taylor and Francis Group
- Year
- 1971
- Tongue
- English
- Weight
- 171 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0030-4948
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π SIMILAR VOLUMES
Derivatives of trans-bicyclo[4.1.0]hept-3-ene with chlorine and bromine substituents the 7 position were synthesized and their thermal rearrangements were examined. Thermolysis of the dichloride leads to the formation of the cis-fused isomer, while heating the dibromide results in ring-expanded prod
## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond