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Degradation of the ruthenium-based metathesis catalyst [RuCl2(CHPh)(H2IPr)(PCy3)] with primary alcohols

✍ Scribed by Donatella Banti; Johannes C. Mol

Book ID: 108187906
Publisher: Elsevier Science
Year: 2004
Tongue: English
Weight: 280 KB
Volume: 689
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2004.07.033

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## Abstract Reaction of the second‐generation Grubbs metathesis catalyst [RuCl~2~(=CHPh)(H~2~IMes)(PCy~3~)] (2) (H~2~IMes = 1,3‐dimethyl‐4,5‐dihydroimidazol‐2‐ylidene) with primary alcohols in the presence of a base produced the complexes [RuClH(CO)(PCy~3~)~2~] (3) and [RuClH(CO)(H~2~IMes)(PCy~3~)]

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