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Degradation of the lanosterol side-chain

✍ Scribed by Lindsay H. Briggs; J.P. Bartley; P.S. Rútledge

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
99 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recent' reports on the degradation of bile acid side-chains have prompted us to record our own with the lanosterol side-chain. Mild degradation of 38-acetoxylanost-8,24-diene (I)

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✍ Shigeo Iwasaki 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 728 KB

## Abstract Irradiation of N‐stearoylimidazole (**1**) gave hexadec‐1‐ene (**4**) in 45% yield, whereas irradiation of N‐(4‐methylstearoyl)imidazole (**13**) possessing a tertiary hydrogen atom γ to the carbonyl group led to 2‐methylhexadec‐1‐ene (**14**) in 62% yield. These results are explained b