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Defects in aluminum quenched from the liquid state

✍ Scribed by G Thomas; R.H Willens


Publisher
Elsevier Science
Year
1964
Weight
800 KB
Volume
12
Category
Article
ISSN
0001-6160

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✦ Synopsis


High purity aluminum was quenched from the liquid state and specimens were examined by transmission electron microscopy. .Very high densities of defects in the form of perfect loops, imperfect loops, and small black spots were observed. The vacancy concentration, as deduced from the number and size of defects in foils quenched from various temperatures, increased with increasing temperature at a much slower rate in the liquid than in the solid. Both the vacancy formation energy and the entropy factor appeared to be considerably reduced above the melting point. concentration was found at the melting point. Also, a discontinuity in the vacancy DEFAUTS DANS L'ALUMINIUM TREMPE A PARTIR DE L'ETAT LIQUIDE De l'aluminium de haute purete a et6 tremp6 a partir de 1'6tat liquide, et lee Bchantillons ainsi trempes ont et6 examines en microscopic Blectronique sur pellicules minces. On a observe une densiti t&s Blev6e de defauts tels que boucles parfaitcs, boucles imparfaites et petitas taches nob-es. La concentration en lacunes, deduite du nombre et de la dimension des defauts dans dea pellicules tremp6es B partir de diverses temperatures, croit avec la temperature, mais beaucoup mains vite dans le liquide que dans le solide. L'bnergie de formation de lacunes et le facteur d'entropie semblent l'un et l'autre &re considerablement reduits au-dessus du point de fusion. continuite dans la loi de la concentration en lacunes. On a aussi observe au point de fusion une dis-GITTERFEHLER IN ABGESCHRECKTEM FLUSSIGEN ALUMINIUM Proben aus hochreinem Aluminium wurden aus dem fliissigen Zustand angeachreckt und im Elektronentransmissionsmikroskop untersucht. Es wurden hohe Dichten von Gitterfehlern in Form von voll-st&ndigen und unvollst&ndigen Ringen sowie kleine schwarze Punkte beobachtet. Die aus der Anzahl und Gr65e der Fehler in den Folien fiir verschiedene Abschrecktemperaturen bestimmte Leerstellenkonzentration nahm bei zunehmender Temperatur im fltissigen Zustand vie1 langsamer zu als im festen. Die Bildungsenergie fiir Leer&&en und der Entropiefaktor scheinen beide erheblich kleiner zu werden oberhalb des Schmelzpunktes. konzentration gefunden. Am Schmelzpunkt wurde ferner ein Sprung der Leerstellen-*


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