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Decyclization of crown ethers. Ring-opening reaction of 18-crown-6 with zirconium tetrachloride

✍ Scribed by Prinz, Horst.; Bott, Simon G.; Atwood, Jerry L.


Book ID
121333741
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
280 KB
Volume
108
Category
Article
ISSN
0002-7863

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Complexes of Lanthanoid Nitrates with 15
✍ Jean-Claude G. BΓΌnzli; Denis Wessner πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 German βš– 860 KB

Complexes between the heavier lanthanoid nitrates Ln(NO~3~)~3~ and 15‐crown‐5 (**1**) and 18‐crown‐6 (**2**) ethers were isolated and characterized. Both 1:1 and 4:3 complexes are formed with each Ln(III) ion, except in the case of Gd and **2**. The thermal transformation of the 1:1 complexes into t