Decoupled structural and non-collinear magnetic phase transitions in Fe(ND3)2PO4

✍ Scribed by Belén F. Alfonso; Camino Trobajo; Carmen Piqué; M. Teresa Fernández-Díaz; Jesús Rodríguez Fernández; Miguel A. Salvadó; Pilar Pertierra; Santiago García-Granda; José R. García; Jesús A. Blanco

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 666 KB
• Volume: 58
• Category: Article
• ISSN: 1359-6454
• DOI: 10.1016/j.actamat.2009.11.016

✦ Synopsis

Interest in Fe(ND 3 ) 2 PO 4 , one of the first three-dimensional structurally linked solids forming Fe-ND 3 bonds, has been renewed recently due to the observation of structural and magnetic phase transitions. This paper reports powder neutron diffraction experiments which show that Fe(ND 3 ) 2 PO 4 crystallizes at room temperature in an orthorhombic (Pnma) crystal structure, but that below T t = 226(5) K the crystal progressively adopts a monoclinic (P2 1 /n) structure via a continuous phase transition, as observed from heat capacity measurements in the temperature range 250-100 K. In addition, neutron diffraction experiments suggest that the magnetic structure is non-collinear with an incommensurate propagation vector kinc ¼ ð1=2 À s; 0; sÞ, with s $ 0.04 reciprocal lattice units (rlus), and that the magnitude of the Fe(III) magnetic moments is close to l Fe = 4.5 l B at T = 2 K, describing a helimagnetic arrangement. To the best of our knowledge, this is an unprecedented magnetic ordering in an iron phosphate lattice. We argue that the proposed magnetic ordering can be explained by means of a model of superexchange interactions involving Fe-O-P-O-Fe paths.