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Decomposition of oligomer in NaH-Y zeolites studied by i.r. spectroscopy

✍ Scribed by Jerzy Datka

Book ID
104290355
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
436 KB
Volume
1
Category
Article
ISSN
0144-2449

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✦ Synopsis

The product of butene oligomerization in NaH-Y zeolites decomposes at high temperatures forming alkene molecules. They may desorb or undergo further transformations in the zeolitic supercages forming alkanes and polycyclic aromatic compounds. This last process occurs in several stages depending on the temperature. The rates of particular stages increase with the concentration and acid strength of the OH groups vibrating at 3640 cm -1. These OH groups were found to participate in the formation of polyenes.

πŸ“œ SIMILAR VOLUMES

I.r. studies of the nature of oligomer i
I.r. studies of the nature of oligomer in NaH-Y zeolites
✍ Jerzy Datka πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 379 KB

Butene oligomerization on NaH-Y zeolites in which some OH groups vibrating at 3640 cm -1 were removed by pyridine adsorption was studied by the i.r. spectroscopy. In each zeolitic supercage in which butene oligomerization takes place one proton is transmitted from the 3640 OH group to the oligomeriz