Decomposition of Lauroyl Peroxide in Benzene and Diethyl Ether
β Scribed by Cass, W. E.
- Book ID
- 126121151
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 383 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0002-7863
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The thermal decomposition of diethyl ether was studied in the temperature range 697.2-760.5 K. The rate constant of reaction (11, and the ratio of the rate constant of reaction (2) to that of (12): (1) CH,CH,OCH,CH, -CH,CH, + CH,CH,O' (21 C H , ~H ~ + CH,CH,OCH,CH~ -+ C ~H ~ + CH,~HOCH,CH, (12) 2CHJ
## Abstract Information is given as to the rates of peroxidation of diethyl ether and diβ__iso__propyl ether under normal laboratory conditions of storage, both with and without inhibitors. Diβ__iso__propyl ether peroxidizes in daylight at least twice as rapidly, and in the dark several times as ra
cyclohexane q diethyl ether g and benzene q diethyl ether g at standard atmospheric pressure over the temperature range 353.2 K to 423.2 K. The non-ideality of the cyclohexane and benzene was fitted using the Kihara potential, and that of the diethyl ether using the Ε½ Stockmayer potential. Cross-ter