Decomposition of formic acid catalyzed by hydrido (phosphonite) cobalt (I) under photoirradiation

Formylation of Alcohol with Formic Acid

Formylation of Alcohol with Formic Acid under Solvent-Free and Neutral Conditions Catalyzed by Free I2 or I2 Generated in situ from Fe(NO3)3·9H2O/NaI

✍ Rostami AMIN; Khazaei ARDESHIR; Alavi-Nik HEIDAR ALI; Toodeh-Roosta ZAHRA 📂 Article 📅 2011 🏛 Elsevier Science ⚖ 221 KB

Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature. I 2 generated in situ from Fe(NO 3 ) 3 •9H 2 O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions. Thi