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Decomposition of amitriptyline hydrochloride in aqueous solution: Identification of decomposition products

✍ Scribed by R. P. Enever; A. Li Wan Po; B. J. Millard; E. Shotton


Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
304 KB
Volume
64
Category
Article
ISSN
0022-3549

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Decomposition of di-tert-butyl nitroxide
✍ T. CΓ‘ceres; C. UrzΓΊa; E. A. Lissi πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 299 KB

Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac