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Decomposition of Alkyl Hypochlorites. The 4-t-Butylcyclohexyl Radical 1

โœ Scribed by Greene, Frederick D.; Chu, Chin-Chiun; Walia, Jasjit

Book ID
126424874
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
624 KB
Volume
29
Category
Article
ISSN
0022-3263

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Rate constants for the reactions of alky
Rate constants for the reactions of alkyl radicals with 1,4-cyclohexadiene
โœ J. A. Hawari; P. S. Engel; D. Griller ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 220 KB ๐Ÿ‘ 1 views

An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t