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Decomposition of alkanes at high pressures and temperatures

✍ Scribed by Zerr, A.; Serghiou, G.; Boehler, R.; Ross, M.

Book ID
120933851
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
215 KB
Volume
26
Category
Article
ISSN
0895-7959

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The rate of methyl radical decomposition
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## Abstract Rate constants are calculated for CH~3~ (+ Ar) ⇄ CH~2~ + H (+ Ar) at the limiting low‐pressure, the limiting high‐pressure, as well as the intermediate fall‐off ranges. The results show that published experimental rate constants for methyl dissociation correspond to the fall‐off region