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Decomposition kinetics of 1,1,2- and 1,1,1-trimethyldisilane

✍ Scribed by Nares, K. E.; Licciardi, G. F.; O'Neal, H. E.; Ring, M. A.


Book ID
127388632
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
688 KB
Volume
9
Category
Article
ISSN
0276-7333

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1,4\_Disilylation of a,@-unsaturated ketones proceeded with l,l-dichloro-l-phenyl-2,2,2\_trimethyldisilane in the presence of a phosphine-palladium catalyst in benzene. Treatment of the disilylation products with an excess of methyllithium generated b-silyl lithium enolates, of which hydrolysis and