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Deceptive similarities in the reactions of iron(I) and cobalt(I) with linear nitriles in the gas phase

โœ Scribed by Lebrilla, Carlito B.; Drewello, Thomas; Schwarz, Helmut


Book ID
127253845
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
675 KB
Volume
109
Category
Article
ISSN
0002-7863

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## Ion -molecule reactions of (acac),M' ions (M = Fe, Co) with macrocyclic thiourea derivatives (L) were studied. The formation of acacML' and acacM(L -H)' were observed. AcacM(L -H)' ions arise from loss of the hydrogen atom of the NH group. The ion peak intensity ratios, Z = (acacML' J/[acacM(L