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Decarboxylation oxydante des acides carboxyliques aliphatiques par un systeme cuivre(i)/oxygene.

✍ Scribed by Olivier Toussaint; Patrice Capdevielle; Michel Maumy


Book ID
104242366
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
253 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new oxidative decarboxylation reaction converts carboxylic acids 1 or 1. (Z q OH) to the corresponding carbonyl compounds 3, in the presence of oxygen and catalytic amounts of copper(I), probably via transient coppernI1) carboxylates.