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Decarboxylation of the 6-nitrobenzisoxazole-3-carboxylate anion catalyzed by cross-linked poly(4-vinylpyridinium) salts

โœ Scribed by Noboru Yamazaki; Seiichi Nakahama; Akira Hirao; Juheiji Kawabata; Hiromichi Noguchi; Yasuzo Uchida

Publisher
Springer
Year
1980
Tongue
English
Weight
274 KB
Volume
2
Category
Article
ISSN
0170-0839

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๐Ÿ“œ SIMILAR VOLUMES

The irrelevance of an intramolecular sal
The irrelevance of an intramolecular salt bridge for solvent-catalyzed decarboxylation-solvent catalysis of the decarboxylation of 4 and6-(2โ€ฒ,4โ€ฒ,6โ€ฒ-trimethylpyridinium)-benzisoxazole-3-carboxylates
โœ D.S. Kemp; J. Reczek; F. Vellaccio ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 113 KB

Previously, we have shown that the benzisoxazole-3-carboxyTates, b, undergo an intermediateless conversion to carbon dioxide and g-cyanophenolate, 5, that is subject to very large solvent rate accelerations. 2 Recently, Klotz and coworkers have demonstrated a pronounced catalysis by aqueous solution