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Decarboxylation as a means of upgrading the heating value of low-rank coals

✍ Scribed by Douglas C. Elliott

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
254 KB
Volume
59
Category
Article
ISSN
0016-2361

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✦ Synopsis

nation over combination pathways as temperatures increase. Since radical-radical combination and radical addition to aromatic systems are commonly thought of as char-forming mechanisms, high temperatures and very short temperature rise times should minimize char formation.

Finally, this work has shown that /?-scission and fragmentation can occur to a significant degree at temperatures commonly employed in coal liquefaction. Thus, it may be expected that /?-scissions and rearrangements of coal-derived radicals occur to a significant degree if radical initiation pathways exist.

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