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Debromination of bromomethyltriphenylphosphonium bromide with triphenylphosphine in alcohols

โœ Scribed by Daniel W. Grisley Jr.

Book ID
104241846
Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
93 KB
Volume
4
Category
Article
ISSN
0040-4039

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โœ I.J. Borowitz; L.I. Grossman ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 178 KB

THE reaction of phenacyl halides with triphenylphosphine is known to give the corresponding phenacyltriphenylphosphonium halides via nucleophilic displacement of halogen. 3 We have found that secondary and tertiary abromoketones, in contrast, react with triphenylphosphine in refluxing benzene-methan