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Dealkylation of coal-derived oil by hydrogen from methanol decomposition: 1. Dealkylation of ethylbenzene as a model of coal-derived oil

โœ Scribed by Run-Ling Ren; Hironori Itoh; Masataka Makabe; Koji Ouchi

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
714 KB
Volume
66
Category
Article
ISSN
0016-2361

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Dealkylation of coal-derived oil by the
Dealkylation of coal-derived oil by the hydrogen generated from methanol decomposition: 3. Reaction of pure compounds
โœ Run-Ling Ren; Hironori Itoh; Koji Ouchi ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 798 KB

Several purecompounds were treated in a flow type reactor with methanol under normal pressure of nitrogen at 800-990ยฐC. Benzene derivatives with shorter alkyl chains can be effectively dealkylated to benzene or toluene, but benzene derivatives with long chains tend to cyclize to diphenjl, naphthalen

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Slurries of Victorian brown coal in either tetralin (1:3) or a hydrogenated creosote oil (HKC 300) (1:3) were reacted with hydrogen in a continuous reactor system both with and without the addition of iron/tin based catalysts. The product yields and distributions from reactions using HKC 300 oil as