Deactivation of homogeneous HRh(CO)(PPh3)3 catalyst in hydroformylation of 1-hexene
β Scribed by R.M. Deshpande; S.S. Divekar; R.V. Gholap; R.V. Chaudhari
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 357 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0304-5102
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Kinetics of HRh(CO)(PPh 3 ) 3 encapsulated in hexagonal mesoporous silica has been investigated for the heterogeneous catalyzed hydroformylation of 1-hexene. The rates of hydroformylation of C 5 -C 12 alkenes, determined under identical conditions, indicated a decreasing trend on increasing the chai
## Abstract The kinetics of the hydroformylation of highβmolecularβweight __cis__β1,4βpolybutadiene in the presence of HRh(CO)(PPh~3~)~3~ and monochlorobenzene as a solvent were studied. The degree of conversion was examined by spectroscopic characterization with Fourier transform infrared and ^1^H