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Deactivation of excited singlet aromatic hydrocarbons by metallic ions in ethanol-water solution

✍ Scribed by M.J. Aguirre; E.A. Lissi; A.F. Olea


Publisher
Elsevier Science
Year
1987
Weight
539 KB
Volume
36
Category
Article
ISSN
0047-2670

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The rate constants for the protonation of "free" (that is, solvated) superoxide ions by water and ethanol are equal to 0.5-3.5 X lO-~M-l.s-' in DMF and AN at 20'. It has been found that the protonation rates for the ion pairs of 0; with the BudN+ cation are much slower than those for "free" 0,. It i