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De Novo Synthesis of (+)-Isofregenedol

✍ Scribed by Riou, Maxime; Barriault, Louis

Book ID: 126330829
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 143 KB
Volume: 73
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo801365z

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An efficient synthesis of (-)-chrysolic acid and (+)-isofregenedol has been achieved from zamoranic acid and sclareol. The characteristic tetrahydronaphtalenic system was obtained by use of a cationic rearrangement of bicyclic systems adequately functionalized. The absolute configuration of the natu

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