Darstellung und kristallstruktur von Ba2Cd3Bi4
✍ Scribed by Gerhard Cordier; Petra Woll; Herbert Schäfer
- Book ID
- 116014256
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 452 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0022-5088
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📜 SIMILAR VOLUMES
Professor Georg Brauer zum 90. Geburtstag gewidmet Inhaltsu È bersicht. Cs 4 SnO 3 wurde in Form xenomorpher Einkristalle durch Umsetzung von SnO mit elementarem Cs erhalten. Die Verbindung kristallisiert triklin in der Raumgruppe P1 mit den Gitterkonstanten a = 737.6(1) pm, b = 1171.3(1) pm, c = 11
Single crystals of Tl 2 PdCl 4 can be obtained by hydrothermal synthesis [1,2]. They show tetragonal symmetry with space group P4/mmm (No. 123). The lattice parameters are a = 7.163(1) A Ê and c = 4.282 (1) A Ê . The atomic arrangement of Tl 2 PdCl 4 is explored by X-ray crystal structure analysis.
The reaction of Se 4 [MoOCl 4 ] and Te 4 [MoOCl 4 ] with SOCl 2 as solvent at 150 °C and 80 °C yields [SeCl 3 ][MoOCl 4 ] and [TeCl 3 ][MoOCl 4 ] respectively within 3 to 6 days as yellow-brown, moisture-sensitive crystals. [TeCl 3 ][MoOCl 4 ] was obtained in the already known monoclinic form, while
Bi 2 ErO 4 I was prepared by solid-state reaction of stoichiometric mixture of BiOI, Bi 2 O 3 and Er 2 O 3 . Bi 2 ErO 4 I is a new compound and the first bismuth rare earth oxide iodide. The crystal structure was determined by the Rietveldmethod (P4/mmm, a = 3,8896(6) A Ê , c = 9,554(2) A Ê , Z = 1)