Darstellung einiger cis-trans isomerer Aminoalkohole
✍ Scribed by Priv.-Doz. Dr. H. Möhrle; H. Baumann
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 541 KB
- Volume
- 301
- Category
- Article
- ISSN
- 0365-6233
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The 1 H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d 8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.
The molecrilar orbital method PC'IIN is applied 10 eight N-n~ot~osi~bstituted amides. Experimentally known geometric properties are reasoilably predicted by minimization of total energy with respect to molecular geometry. The bame procedure shows that molecular deformations during rotation around t