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Dalton communications. ansa-Bridged tris(cyclopentadienyl) compounds of zirconium and hafnium: X-ray crystal structures of [M{Me2C(?5-C5H4)2}(?5-C5H5)Cl](M = Zr or Hf)

✍ Scribed by Diamond, Gary M.; Green, Malcolm L. H.; Popham, Neil A.; Chernega, Alexander N.


Book ID
121495125
Publisher
The Royal Society of Chemistry
Year
1993
Tongue
English
Weight
328 KB
Volume
16
Category
Article
ISSN
1472-7773

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Synthesis and Reactivity of Alkylzirconi
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## Abstract The monoalkyl complexes [Zr{Me~2~Si(Ξ·^5^‐C~5~Me~4~)(Ξ·^5^‐C~5~H~3~R)}(Rβ€²)Cl] [R = Me, Rβ€² = CH~2~Ph (1); R = Me, Rβ€² = CH~2~SiMe~3~ (2); R = __i__Pr, Rβ€² = CH~2~Ph (3); R = __i__Pr, Rβ€² = CH~2~SiMe~3~ (4); R = SiMe~3~, Rβ€² = CH~2~Ph (5); R = SiMe~3~, Rβ€² = CH~2~SiMe~3~ (6)] have been synthesiz