Dactylomelol, a new class of diterpene from the sea hare aplysia dactylomela
✍ Scribed by Dulce M. Estrada; José L. Ravelo; Catalina Ruiz-Pérez; Julio D. Martín; Xavier Solans
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 128 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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Four new halogenated chamigrenes have been isolated from the sea hare, the (E)-and (Z)-9-(bromomethylidene)-1,2,5-trimethylspiro[5.5]undeca-l,7-dien-3-ones (11 and 10, resp.) the structures of which were deduced by NMR spectroscopy and by comparison with a known relative, the (8R,9R)-8-bromo-9-chlor
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6S,10S)-3,10- Dimethyl-7,11-dimethylidenespiro[5,5]undec-2-en-4-one (1), a new rearranged chamigrane-type sesquiterpenoid with two sp 2 -hybridized carbons in α-positions to the spiro-atom, was isolated from the alcoholic extract of the sea hare Aplysia sp. and its structure and absolute configurati