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DABCO catalyzed coupling of α-keto esters with acrylonitrile and methyl acrylate

✍ Scribed by D. Basavaiah; T.K. Bharathi; V.V.L. Gowriswari


Book ID
108383051
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
130 KB
Volume
28
Category
Article
ISSN
0040-4039

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Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Rucatalysts affords a-keto esters and a-keto amides in 44-84% yield. These conversions can also be effected with RuO,. Oxidations based on iodosylbenzene are of current interest in connection with model studies for peroxidase