d10-d10 Interactions: multinuclear copper(I) complexes
β Scribed by Merz, Kenneth M.; Hoffmann, Roald
- Book ID
- 120581584
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 776 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## I) Copper(I) a b s t r a c t Model compounds are used to study the metallophilic attraction between gold and copper atoms. Ab initio calculations on dimers and tetramers in different distributions of the simplified units are analyzed. An attraction is found for all models and there is a reasona
The reaction of CuO'Bu with CO, and 'Pr,NH in the presence of PPh, gives the dialkylcarbamato complex [Cu(O,CN'Pr,)(PPh,),] (1). The CO,/R,NH system (R = Me, Et) in an appropriate organic medium reacts with Ag,O giving the corresponding N,N-dialkylcarbamato complexes of analytical formula [Ag(O,CNR,