Cytotoxic Rhodium(III) and Iridium(III) Polypyridyl Complexes: Structure–Activity Relationships, Antileukemic Activity, and Apoptosis Induction
✍ Scribed by Mara Dobroschke; Yvonne Geldmacher; Ingo Ott; Melanie Harlos; Lisa Kater; Laura Wagner; Ronald Gust; William S. Sheldrick; Aram Prokop
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 523 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1860-7179
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📜 SIMILAR VOLUMES
## Abstract Bis(ethene) complexes of rhodium(I) and iridium(I) with 8‐quinolylcyclopentadienyl ligands (Cp^Q^ and Cp^Q^\*) were oxidized by a photochemically induced reaction with chlorine‐containing solvents or by treatment with iodine. Upon this oxidation, the quinoline ring rotates and the N don
## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat