Cytochromes P450 catalyze oxidation of α,β-unsaturated aldehydes
✍ Scribed by Immaculate Amunom; Laura J. Stephens; Viola Tamasi; Jian Cai; William M. Pierce Jr.; Daniel J. Conklin; Aruni Bhatnagar; S. Srivastava; Martha V. Martin; F. Peter Guengerich; Russell A. Prough
- Book ID
- 116177946
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 561 KB
- Volume
- 464
- Category
- Article
- ISSN
- 0003-9861
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📜 SIMILAR VOLUMES
The oxidation of aldehydes to a@-unsaturated aldehydes has been performed by a sequence of reactions involving conversion into aldimines, chlorination at the a-position to form a-chloroaldimines, base-induced dehydrochlorination and h drol sis The four-step transformation can be executed without iso
## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p