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Cyro-vibrational spectroscopy of blue copper proteins

✍ Scribed by William H. Woodruff; Kenneth Norton; Basil I. Swanson; Herbert A. Fry; Bo G. Malmström; Israel Pecht; David F. Blair; Wilson Cho; Gary W. Campbell; Vanessa Lum; Vincent M. Miskowski; Sunney I. Chan; Harry B. Gray


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
243 KB
Volume
79
Category
Article
ISSN
0020-1693

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1 H-and 13 C-NMR spectroscopy is applied to investigate the Cu A and type 1 active sites of copper proteins in solution. The analysis of hyperfine shifted 1 H resonances allows the comparison of the electron spin density delocalization in the Cu A site of the wild-type soluble domains of various cyt