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Cynaratriol, ein neues Guajanolid aus der Kardone Cynara cardunculusL. und der Artischocke C. scolymusL.(Compositate)

✍ Scribed by Heinz O. Bernhard; Kurt Thiele; Ernö Pretsch


Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
489 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis


Cynaratriol, a new guajanolide from Cynara cardunculus L. and C. scolymus L. (Compositae)

A new guajanolide given the name cynaratriol (4) was isolated from the leaves of Cynara cardunculus L The structure of 4 and its derivatives 3, 11, 13‐triacetylcynaratriol (5) and 3, 13‐dibenzoyl‐cynaratriol (6) was deduced on the basis of IR.‐, ^1^H‐NMR.‐, ^13^C‐NMR.‐ and mass spectroscopic data. 4 is also present in C. Scolymus L. as shown by GC./MS. analysis. The same absolute configuration is suggested for 4 as found for all other Cynara sesquiterpenes.