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Cyclopropylcarbinyl p-toluenesulfonate solvolysis. IV. Correlation with cholesteryl tosylate solvolysis rates

✍ Scribed by Roberts, Donald Duane.; Watson, Thomas M.


Book ID
126063457
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
551 KB
Volume
35
Category
Article
ISSN
0022-3263

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## Abstract The rates of solvolysis of secondary __p__‐toluenesulfonates in acetic acid or 97% trifluoroethanol are interpreted in terms of strain changes between substrate and the corresponding ketone. Such strain changes are obtained from force‐field calculations (Ξ”__E__~st~) and from equilibrati