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Cyclopropenone-Catalyzed Direct Conversion of Aldoximes and Primary Amides into Nitriles

✍ Scribed by Rai, Ankita; Yadav, Lal Dhar S.

Book ID
120039797
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
354 KB
Volume
2013
Category
Article
ISSN
1434-193X

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✍ Necdet Coşkun; Nevin Arikan πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 287 KB

Ab~mrt: O-Arylcarbamoylated hydroxylamine tosylate reacts with aldehydes at room temperature to give the corresponding O-earbamoylated oximes. The reaction of earbamoylated hydroxylamine with aromatic aldehydes in THF or in toluene at reflux affords the corresponding nitriles and anilinium tosylate