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Cyclopropanes. XX. Electrochemical reduction of (+)-S-1-bromo-1-methyl-2,2-diphenylcyclopropane

✍ Scribed by C.K. Mann; J.L. Webb; H.M. Walborsky

Book ID: 104213876
Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 346 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72409-9

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✦ Synopsis

In order to gain some insight into the mechanism of metallation.and of homogeneous and heterogeneous dissolving metal reductions, we have undertaken a study involving the reduction of optically active (+)-(S-)-l-.bromo-1-methyl-2,2-diphenylcyclopropane. This system is ideally suited for such an investigation since the optical purities and tht absolute configurations of both the starting material and the product, l-methyl-2,24iphenylcyclopropane, are known'. Moreover, in contrast to most

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